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Why don't radon and krypton bond easily?

By Radon411 Editorial TeamUpdated How we research

Short answer

Radon and krypton do not bond easily because each has a full outer shell of eight valence electrons, 6s2 6p6 for radon and 4s2 4p6 for krypton, leaving little tendency to gain, lose or share electrons. Both are noble gases in group 18, though radon is not completely unreactive: fluorine has been reported to react with it.

Next step: a test is the only way to know your home's level. How to test your home

The electron configurations show it. Krypton is [Ar] 4s2 3d10 4p6 and radon is [Xe] 6s2 4f14 5d10 6p6. The outermost shell of each, 4s2 4p6 for krypton and 6s2 6p6 for radon, holds 2 + 6 = 8 electrons and is full. Asked which statement best explains why radon and krypton do not bond easily with other elements, the best answer is the one about a complete set of valence electrons. Compared as Lewis structures, the two look alike: Kr and Rn each carry eight dots in four pairs, one for each valence electron.

The behavior follows from that. Both are noble gases with an oxidation state of 0, and radon is essentially inert. Because radon is a noble gas, it releases from any chemical bonds that attach it, and it can travel far enough to reach groundwater or the air.

Not bonding easily is not the same as never bonding. Fluorine has been reported to react with radon, forming a fluoride, and radon fluoride is the only confirmed compound of radon.

For homes, what matters is that radon is a gas: it can move up from the ground into buildings through openings in floors or walls in contact with the ground.

What to do next: read the chemistry section of the radon element guide, and test the lowest lived-in level of your home.

The short explanation: full outer shells

Radon and krypton are both noble gases in group 18, and both end their electron configurations with a full outer shell of eight electrons: 4s2 4p6 for krypton, 6s2 6p6 for radon. An atom with a full shell has no unpaired electron to share and nothing to fill, which is why both form bonds so rarely. Krypton is element 36 and radon element 86, in the same column of the table.

Krypton and radon side by side
PropertyKryptonRadon
Atomic number3686
Electron configuration[Ar] 4s2 3d10 4p6[Xe] 6s2 4f14 5d10 6p6
Outer shell4s2 4p6 (8 electrons)6s2 6p6 (8 electrons)
First ionization energy14.000 eV10.745 eV
Atomic radius202 pm220 pm
Boiling point119.93 K211.45 K

The exam answer

A common chemistry question asks which statement best explains why radon and krypton do not bond easily with other elements. The answer is the one about valence electrons: each has a complete set of eight in its outer shell. Answers about atomic mass do not explain it: radon is far heavier than krypton, 222.01758 against 83.80, yet both behave alike.

Where the eight electrons come from

In each configuration, the noble gas in brackets is the core: argon's 18 electrons for krypton, xenon's 54 for radon. What follows fills the next shell to eight outer electrons. Xenon, between them in the group, follows the same pattern with 5s2 5p6.

Outer shells down group 18 (our count from each configuration)
ElementCoreOuter shellValence electrons
Krypton (36)[Ar]4s2 4p68
Xenon (54)[Kr]5s2 5p68
Radon (86)[Xe]6s2 6p68

Drawn as Lewis dot structures, Kr and Rn look alike: the symbol with eight dots in four pairs. See how many valence electrons radon has.

Not easily is not never

Radon is essentially inert, but not completely. Fluorine has been reported to react with radon, forming a fluoride, and radon fluoride is the only confirmed compound of radon. Its oxidation states are listed as 6, 2 and 0.

Radon's bonding profile
PropertyRadon
ReactivityEssentially inert
Confirmed compoundsRadon fluoride only
Oxidation states6, 2, 0
Electronegativity (Allen scale)2.6
First ionization energy10.745 eV

Radon's first ionization energy is lower than krypton's, 10.745 eV against 14.000 eV, so by that measure radon holds its outer electrons less tightly than krypton does.

Why it matters that radon does not bond

Since radon is a noble gas, it releases from any chemical bonds that attach it, and it may travel far enough to reach groundwater or the air. It comes from the natural decay of uranium and radium in nearly all rocks and soils and can move up from the ground into buildings through openings in floors or walls in contact with the ground.

Questions about radon and krypton bonding

Why do radon and krypton not bond easily with other elements?

Both have a full outer shell of eight valence electrons, so they have little tendency to gain, lose or share electrons.

Are radon and krypton in the same group?

Yes. Both are noble gases in group 18; krypton is element 36 and radon element 86.

Can radon form compounds?

Rarely. Fluorine has been reported to react with radon, and radon fluoride is its only confirmed compound.

How many valence electrons do radon and krypton have?

Eight each: 4s2 4p6 for krypton and 6s2 6p6 for radon.

What is krypton's electron configuration?

[Ar] 4s2 3d10 4p6, with 36 electrons in all and eight in the outer shell.

Which holds its electrons more tightly, krypton or radon?

Krypton. Its first ionization energy is 14.000 eV, against radon's 10.745 eV.

Is radon's inertness why it gets into homes?

It helps: as a noble gas, radon releases from chemical bonds and can travel far enough to reach the air, then enter buildings from the ground.

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