The electron configurations show it. Krypton is [Ar] 4s2 3d10 4p6 and radon is [Xe] 6s2 4f14 5d10 6p6. The outermost shell of each, 4s2 4p6 for krypton and 6s2 6p6 for radon, holds 2 + 6 = 8 electrons and is full. Asked which statement best explains why radon and krypton do not bond easily with other elements, the best answer is the one about a complete set of valence electrons. Compared as Lewis structures, the two look alike: Kr and Rn each carry eight dots in four pairs, one for each valence electron.
The behavior follows from that. Both are noble gases with an oxidation state of 0, and radon is essentially inert. Because radon is a noble gas, it releases from any chemical bonds that attach it, and it can travel far enough to reach groundwater or the air.
Not bonding easily is not the same as never bonding. Fluorine has been reported to react with radon, forming a fluoride, and radon fluoride is the only confirmed compound of radon.
For homes, what matters is that radon is a gas: it can move up from the ground into buildings through openings in floors or walls in contact with the ground.
What to do next: read the chemistry section of the radon element guide, and test the lowest lived-in level of your home.