A system only protects the home while it works. Look for a clear label, a warning device such as a manometer, a fan outside the living space and an exhaust above the roof, and ask whether any warranty transfers to you.
Then test. Make sure the vent fan is operating properly, have it repaired first if it is not, and keep the system running for the whole test, placed in the lowest level you might use regularly.
What to do next: request the seller's results and system information now, and book a test with the system on as part of your inspection period.

