Radon in a home's air comes from two main sources, the soil and the water supply, and the soil is usually the much larger risk. That is why the air test comes first; if it finds a radon problem and your water comes from a well, test the water next.
Groundwater from wells normally carries more radon than surface water, and radon dissolved in water is released into indoor air when the water is used. Most of the risk from radon in water comes from that release during showering and other household use.
Water sampling follows its own protocol, MW-RN-2020, which covers collecting and transporting water samples and transferring them to a measurement device. Follow the lab's collection instructions exactly.
What to do next: test the air in the lowest lived-in level if you have not. If you have a private well, ask your state radon office which labs measure radon in water, and if the result is high, look into point-of-entry treatment.